Description

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Compétences requises

Etudiant motivé détenteur d’un Master en chimie, option chimie organique. Bon niveau, théorique et pratique en synthèse organique moderne.

Bibliographie

1. “[2,3]-Sigmatropic Rearrangement of Ynamides: Preparation of α-Amino Allenephosphonates.” Gomes, F.; Fadel, A.; Rabasso, N. J. Org. Chem. 2012, 77, 5439–5444.
2. “Selective Reduction of Amino Allenephosphonates: Preparation of α-Amino Vinylphosphonates.” Adler, P.; Gomes, F.; Fadel, A.; Rabasso, N. Eur. J. Org. Chem. 2013, 7546–7555.
3. “Strategies for the synthesis of α- and β-amino vinylphosphonate.” Adler, P.; Fadel, A.; Rabasso, N. Tetrahedron 2014, 70, 4437–4456.
4. “From acyclic to cyclic α-amino vinylphosphonates by using ring-closing metathesis” Adler, P.; Fadel, A.; Prunet, J.; Rabasso, N. Org. Biomol. Chem. 2017, 15, 387-395.
5. “Cerium(IV) ammonium nitrate mediated 5-endo-dig cyclization of α-amino allenylphosphonates to spirodienones.” Adler, P.; Fadel, A.; Rabasso, N. Chem. Commun. 2015, 51, 3612–3615.
6. “Synthesis of N-Sulfonyl Ynamido-Phosphonates: Valuable Partners for Cycloadditions.” Perez, V.; Fadel, A.; Rabasso, N. Synthesis, 2017, 49, 4035-4044

Mots clés

Chimie organique, énamines, cycloaddition, photoredox