Description

PRISM programme

The PRISM (PhD Research Programme for International Training in Sustainable Soft Matter) programme has launched its first call for applications, offering up to 14 fully funded PhD fellowships starting from 1 March 2027 at Paris Sciences & Lettres (PSL) University. The programme trains researchers to address ecological transition challenges through sustainable soft matter science, with projects focused on eco-friendly chemical processes, circular economy, renewable energies, and carbon capture, storage, and valorisation. Co-funded by the European Union under Horizon Europe MSCA COFUND (Grant Agreement 101261637) and partner institutions.

Applications must be submitted via the PRISM website (https://prism.psl.eu/en/) by 31 October 2026.

 

The PhD project

CO₂ capture, whether from industrial sectors or directly from the atmosphere, has gained significant global attention due to the growing climate crisis. For the last decades, the most widely used CO₂ capture systems have been based on amine scrubbing technology. However, CO₂ release requires high temperatures and substantial energy input, causing significant amine degradation over time. This limits the economic viability of scrubbing low-concentration CO₂ sources, such as post-combustion gases and atmospheric air.[1]

Much recent work has focused on physically and chemically supported amine-based polymers that can be regenerated under mild conditions.[2] Many sorbents display promising CO₂ uptake capacities thanks to their high surface area. However, few studies have reported solid sorbents effective in humid environments, where water vapor competes with CO₂ for adsorption sites or condenses to block the sorbent’s pores. There is thus a need for nonvolatile sorbents that can operate reversibly under wet conditions and be regenerated at relatively low temperatures.

A promising approach by Hoshino and co-workers[3] uses hydrogel micro- and nanoparticles that reversibly absorb and release CO₂ between 30 and 75 °C. These particles are based on cross-linked copolymers of N-isopropylacrylamide (NIPAm) and acrylamides with pendant tertiary amine groups. Above the lower critical solution temperature (LCST) of the poly(NIPAm) domains, the basicity of the tertiary amines is strongly decreased due to the lower dielectric constant in the dehydrated state. This phase change enables reversible CO₂ capture at low temperatures. However, the low concentration of amine groups results in significantly lower absorption capacity per volume compared to conventional amine scrubbing,[3] and the system lacks sufficient reactivity to capture CO₂ directly from the atmosphere.[4]

In this PhD project, called CAPTURE, we aim to leverage the C3M laboratory’s expertise in making functional polymeric materials to dramatically enhance the CO₂ capture capabilities of thermo-responsive gels. We believe that introducing synergistic functional groups is essential to this new approach. This project will strongly benefit from collaboration with TotalEnergies in the frame of the PICTE joint laboratory with the ESPCI Paris - PSL, working on physical chemistry for the energy transition, as well as an international secondment focused on coupled rheological techniques.

The project will entail the synthesis of new hydrogel particles via (controlled) radical polymerization, followed by a thorough study of their physicochemical, thermomechanical, rheological, and morphological properties. Assessing the pKa of the pendant functional groups as a function of composition and temperature will be key to rationalizing their behavior. Reversible CO₂ capture and release experiments will benchmark the performance of these new materials.

CAPTURE is expected to result in publications in leading scientific journals, oral presentations at national and international conferences, and potentially patent applications. Our collaboration with TotalEnergies will be critical in guiding the potential industrialization of this technology.

 

3i dimensions

INTERNATIONAL: CAPTURE will include an international secondment of at least one month in the laboratory of Dr. Daniele Parisi, assistant professor at the University of Groningen (NL). Our team already collaborates with Dr. Parisi in the frame of an EU doctoral network called ReBond (HORIZON-MSCA-2022-DN-01, REA Grant Agreement No. 101119786; https://www.rebondproject.eu/). Dr. Parisi is a recognized expert in the linear and nonlinear rheology of soft materials, and he has particular expertise in rheo-Raman techniques. These experiments will be ideal for correlating the structure, viscoelasticity, and CO₂ capture capabilities of the materials developed in the frame of CAPTURE.

INTERSECTORAL: CAPTURE will be conducted in collaboration with TotalEnergies represented by Dr. Stéphane Jouenne, CO2 Capture Project Coordinator of TotalEnergies (Pau, FR) and Dr. Enric Santanach-Carreras (HDR), researcher at the Pole d’Etudes et Recherche de Lacq (PERL). Furthermore, CAPTURE will be included in the newly-launched joint laboratory called PICTE (PhysIcoChimie pour la Transition Energétique) between TotalEnergies and several laboratories at the ESPCI Paris - PSL, of which the C3M is a founding member. The research proposed in CAPTURE perfectly addresses a key challenge targeted by the PICTE laboratory, which is to study and optimize the shaping of adsorbent materials for CO₂ capture with a focus on direct air capture (DAC) technologies. 

INTERDISCIPLINARY: The CAPTURE project is inherently interdisciplinary, traversing concepts of chemistry and physics. It entails molecular and macromolecular organic synthesis, advanced characterization techniques (which cover the chemical, physical, and mechanical aspects of the new materials), polymer processing, and engineering of CO2 capture systems.

 

Salary

The PRISM programme offers a competitive salary above the national average for PhD candidates in France to attract and support excellent researchers. Doctoral candidates will receive an approximate net monthly salary of €2,200, with additional family and mobility allowances available for eligible fellows. The salary is subject to French income tax, with the exception of the family and mobility allowances. Depending on the candidate's individual tax situation, income tax may represent approximately 2–5% of the net salary and is levied by the French tax authorities independently of the employer.

 

Eligibility criteria

1. At the time of application, candidates must be in possession of their Master’s degree or equivalent/postgraduate degree which formally entitles them to start a doctorate. All applicants with a doctoral degree are ineligible.
2. A minimum English proficiency level of C1 (Advanced) is required for applicants from non-English-speaking countries. No French language skills are required.
3. Applicants must fulfil the transnational mobility rule: open to all nationalities but all incoming applicants must not have resided or carried out their main activity (work, studies, etc.) in France for more than 12 months in the 3 years immediately prior to the call for applications deadline.
4. Applicants must be available to start the program on schedule: 1st March 2027.
5. Completeness of the application, submitted in English on the PRISM dedicated website, before the deadline of 31 October 2026.

 

Name of the school of PSL

ESPCI - PSL (Ecole Supérieure de Physique et de Chimie Industrielles de la ville de Paris)

Research Unit

Laboratoire Chimie Moléculaire, Macromoléculaire, Matériaux (UMR7167, C3M)

The C3M lab develops and exploits synthetic chemistry at all scales, from molecules to materials. The unit is organized into three complementary teams, creating a continuum of well-identified and recognized expertise in molecular and macromolecular synthesis, and in the physical chemistry of soft matter. The research topics developed in the unit and the methodologies implemented reflect the broad spectrum of skills and expertise of its members. Nevertheless, they can be grouped according to generic themes, revealing thematic coherence and the possibility of synergies.

– Exploring molecular diversity: strained cycles, development of exchangeable reactions

– Sustainable chemistry: catalysis with naturally abundant metals, enzymatic catalysis, photocatalysis, continuous flow chemistry, solvent-free syntheses, reactive extrusion.

– Materials using dynamic covalent chemistry

– Architectural systems for medicine, robotics and polymer materials

– Formulation of functional colloidal gels and glasses

 

Supervision

Supervisor: Nathan VAN ZEE nathan.van-zee@espci.psl.eu

Co-supervisor: Renaud NICOLAŸ renaud.nicolay@espci.psl.eu

Co-supervisor: Enric SANTANACH CARRERAS enric.santanach-carreras@totalenergies.com

Candidates are encouraged to contact the project supervisors to discuss the proposed research topics before applying. All projects are open PhD projects, meaning that the research plan will be further developed collaboratively by the selected doctoral candidate and the supervisors.

Skills required

The candidate must hold a Master’s degree (or equivalent) in molecular chemistry, supramolecular chemistry, and/or polymer chemistry. A keen interest in multidisciplinary research is essential, along with a passion for conducting fundamental research at the intersection of academic and industrial interests. Practical experience in academic laboratories specializing in molecular and/or polymer chemistry would be a significant asset, as would experience in characterizing the CO₂ capture properties of materials.

Bibliography

References: [1] G. T. Rochelle, Science 2009, 325, 1652. [2] S. Singh et al., J. Mater. Chem. A 2026, Advance Article. [3] Y. Hoshino, et al., J. Am. Chem. Soc. 2012, 134, 18177. [4] R. Honda, et al., Polym. J. 2020, 53, 157.

Keywords

CO₂ absorption, functional polymers, microgels, temperature-responsiveness, phase transitions